A new look at the hydrogen economy

by Kas Hemmes, Projectleader, VG2 the greening of gas
TPM Coordinates ‘The Greening of Gas’ Project [VG2]

To mix hydrogen into the domestic gas network: that is the challenge that those taking part in the EET-subsidized project, ‘The Greening of Gas’ have set themselves. Project coordinator Dr Kas Hemmes (Associate Professor with the Energy and Industry section) describes the many technical and administrative difficulties of this promising idea.

Under the Kyoto Climate Treaty, the Netherlands is expected to reduce its emission of greenhouse gases by six per cent (compared to 1990 levels). The main greenhouse gases produced by the combustion of fossil fuels such as oil, gas and coal are NOx (nitrogen oxides), SO2 (sulphur dioxide) and CO2 (carbon dioxide). The idea of using hydrogen as a supplementary energy source emerged in the 1970s. Hydrogen has a significant advantage in that its combustion produces only water and no greenhouse gases. “Because the environmental benefits are so obvious, some people do not understand why the idea was not implemented a long time ago,” states Kas Hemmes. “Perhaps they think we can just dig a well and pump hydrogen out. Unfortunately, it’s not that simple. Pure hydrogen does not occur naturally. It has to be derived from other energy sources such as natural gas, coal or biomass. It can also be extracted from water by means of electrolysis.”

Hemmes, who studied experimental and theoretical physics in Groningen, gained his doctorate in 1986 with his research into magnetic recording. However, he soon became interested in energy research. For fifteen years, he conducted research into fuel cells with the Material Sciences and Engineering department of Delft University of Technology. For the last eighteen months he has been involved in the systems design for a national hydrogen distribution infrastructure and the design of transition processes towards a hydrogen economy. This work has been conducted within TPM as part of the ‘Greening of Gas’ project, financed by the Ministry of Economic Affairs, the Ministry of Education, Culture and Science and the Ministry of Housing, Spatial Planning and the Environment (VROM) under the Economy, Ecolgy and Technology (EET) programme.

Economic interests
The use of hydrogen as an energy source is not only hampered by its limited availability. Another problem is that it is difficult to store or trans-port in large quantities. “If we want to use hydrogen on a large scale, there would have to be a network of pipelines covering the entire country,” explains Hemmes. “Needless to say, this would entail a huge investment. Our idea therefore becomes even more attractive: we are investigating the possibility of using the existing gas infrastructure. By mixing hydrogen into the natural gas, at least the transport problem is solved.” Because this ‘new look at the hydro-gen economy’ entails investigating a large number of technical and administrative considerations, the project has been split into two parts. The technical questions are being addressed by the Delft Laboratory for Process Equipment, (API), the Faculty of Civil Engineering and Geosciences, Electrabel, EcoCeramics, the Netherlands Organization for Applied Scientific Research (TNO), Gasunie and the Universities of Groningen and Eindhoven. These partners are concerned with such aspects as fundamental combustion research, the effect of hydrogen/ biogas/natural gas mixtures on pipeline materials, gas turbines and gas-fired engines, research into new burner types, and the safety aspects of transporting and distributing hydrogen-rich gas mixtures.

The other part of the project, coordinated by Dr Hemmes, involves TPM working alongside Hoek Loos, the Faculty of Civil Engineering and Geosciences, Schouten Research, Energy + i.d. and the City Of Rotterdam Port Authority (GHR). It is primarily concerned with infrastructural development in the technical, socio-economic and juridical contexts. Research is being conducted into the costs-returns ratio, national and international legislation, and the impact of the liberalization of the gas market. “From the technical perspective, mixing hydrogen with natural gas in the existing network could well prove the best solution, but this does not necessarily mean that it will actually be implemented. There are many factors to be taken into consideration. We live in an era in which economic interests are paramount. Everything must be cost effective and market forces must be allowed to prevail. We are looking at both the demand and supply side of hydrogen/ natural gas mixtures. We are designing a suitable infrastructure and conducting dynamic modelling for the transition process. In the final phase, we hope to implement our ideas in the Rotterdam harbour district.”

Quality
First and foremost, TPM’s part of the project involves investigating existing and potential hydrogen production techniques. These include the ‘non-conventional’ techniques such as extracting hydrogen from biomass. If this is indeed feasible, countless interesting scenarios emerge. “Suppose a group of farmers have a pile of surplus biomass which is serving no other purpose. They could use it to produce hydrogen which they will then add to the gas network, wherever they happen to be. This may seem somewhat far-fetched, but in the new liberalized gas market anyone will be allowed to produce and supply gas, in theory at least. Of course, existing legislation must be observed.

Gas must comply with certain quality requirements and must have a certain calorific value, as expressed by the Wobbe index. It is still uncertain whether natural gas to which hydrogen or biogas has been added will meet the quality requirements. If not, it may be appropriate to amend the legislation allowing gas of a different quality to be supplied. At the moment, the standard is the ‘Slochteren norm’, with all domestic gas-burning equipment and most industrial equipment designed, built and regulated accordingly. We simply do not know whether consumers and industrial users will be prepared to convert to new burners and gas turbines, as they were required to do in the 1960s when the Slochteren gas pocket first came ‘on line’.”

Consequences for the infrastructure
The addition of hydrogen to gas would not be without consequences for the existing gas infrastructure. Hydrogen has a lower calorific value than natural gas, which means that volumes must be increased.


Hydrogen-powered buses in Germany
Kas Hemmes gives a brief refresher course in chemistry: “Natural gas is actually methane, or CH4, a com-pound of one part C and two of H2. One part of H2 has roughly one third of the calorific value of CH4. This means that if you add ten per cent hydrogen (by volume) to the natural gas, you have added only three per cent energy value. In order to main-tain the same calorific value, you have to transport a much higher volume of gas. It is not certain whether the existing network of pipes would be able to cope.”

Another interesting research question with regard to the infrastructure is where the hydrogen should be physically introduced to the network. Gas is always transported in only one direction along each pipe, whereby the hydrogen can only be added ‘upstream’. This is the major difference between gas and electricity, which in theory can be returned from any point in the network.

Conversion losses
The sub-project ‘Demand-side Analysis of H2/NG Infrastructure’ (NG stands for Natural Gas) is studying the possible applications for the hydrogen/gas mixture. Could consumers use it to fuel a central heating boiler? Would industry be better off, or would the disadvantages outweigh the benefits? “Of course, we want to ensure that there are only advantages,” states Hemmes, “since this would represent a significant motive for getting the process off the ground. For industry, it is extremely important that the use of hydrogen serves to reduce CO2 emissions, as this will enable future economic gains to be made. The Vogtländer Commission, appointed by the Ministry of VROM, favours a system of trading in ’emission rights’. This could prove a valuable and efficient instrument in tack-ling the emission of greenhouse gases. Companies which produce relatively little CO2 could make extra profit by selling their emission rights, their ‘quota’ as it were. This system is particularly interesting for the metals industry and companies such as Corus, which use cokes to convert metal oxides into the finished product, thus producing enormous quantities of CO2.”

“In the long term, it seems economically viable for industry to convert, at least partially, to the use of hydrogen/ natural gas mixtures. Unfortunately, this is not the case in the short term. We run up against a paradox. A familiar industrial process whereby hydrogen can be produced from natural gas itself is steam methane reforming. The petrochemicals industry uses this process on a large scale to remove sulphur compounds from crude oil. However, it always entails conversion losses: twenty per cent of the energy is simply lost. In the first instance therefore, if industry wishes to convert to the use of hydrogen, greater quantities of natural gas will be required, which will cost more.”

Incentives
It is therefore extremely important that additional benefits are created for hydrogen mixtures, apart from the reduction in diffuse CO2 emissions. The transition process must include incentives to encourage consumers and industry to adopt the new fuel form. Transition -management and dynamic modelling of transition processes fall within the TPM sphere of expertise. What technical and administrative instruments can serve to promote a government objective such as emissions reduction, and how can one monitor the results? Kas Hemmes suggests one possibility: “If hydrogen is introduced to the main gas net-work, every household and every company in the Netherlands will be able to use it. One of the concepts we are investigating is that of micro-generation. Every building would have a fuel cell powered by hydrogen and producing electricity. Some energy is converted into heat during this process and would normally be lost. In our system, it can be used for heating. The gas is therefore used to the full. Because H2 will already be in the gas, no reformer (a sort of miniature chemical conversion plant) will be required. The fuel cell will filter the hydrogen out, as it were.”

Another possible application for the mixture is as an automotive fuel. A 80/20 mixture of hydrogen and natural gas (which is already on the market under the trade name ‘Hythane’) has extremely good combustion properties. It has lower NOx emissions, whereby great environmental gains can be made when used in cars with an internal combustion engine. Moreover, provided good separation techniques become available, the hydrogen can be extracted from the mixture for use in electric cars equipped with fuel cells. Research is also being conducted into possible industrial uses for the CO2 which is a by-product of hydrogen production. This could be used in oil and methane abstraction processes.

Path dependency
Hemmes concedes one fundamental problem in all this. “Although the addition of hydrogen to the gas net-work does seem to have some major advantages, there is a danger that this approach will lead to ‘path dependency’. It would stand in the way of a transition to a 100% hydrogen economy, since once the proportion of hydrogen in the mix has been established, it will not be possible to increase this time after time. Doing so would require further modifications to industrial gas turbines, which is an extremely expensive undertaking.

There is a very high likelihood that if this option is adopted, the percentage of hydrogen in the mix will be pegged at 5 or 10% for ever more. A one-step transition may therefore be preferable. We in the department of TPM are working alongside our partners to identify the pros and cons of all the various options.”


Visit also the conference about  the future of Energy – the Hydrogen Economy? 


Share This Post
Have your say!
00

Customer Reviews

5
0%
4
0%
3
0%
2
0%
1
0%
0
0%
    Showing 0 reviews
  1. Write more, thats all I have to say. Literally, it seems as though you relied on the video to make your point.
    You definitely know what youre talking about, why waste your intelligence on just posting videos to your site when you could be giving us something enlightening to read?
    0

    0

    You have already voted!

    Reply
  2. What’s up to every single one, it’s genuinely a good for me to go to see this website,
    it consists of precious Information.
    0

    0

    You have already voted!

    Reply
  3. I absolutely love your site.. Great colors & theme.

    Did you develop this amazing site yourself? Please reply back as I’m wanting to create my
    own blog and would love to find out where you got this from or just what the theme is
    named. Appreciate it!

    0

    0

    You have already voted!

    Reply
  4. Piece of writing writing is also a excitement, if you be familiar with afterward you can write otherwise it is
    complicated to write.
    0

    0

    You have already voted!

    Reply
  5. Magnificent goods from you, man. I have understand your stuff previous
    to and you’re just extremely magnificent. I really like what you’ve acquired here, really
    like what you’re saying and the way in which you say it.
    You make it entertaining and you still care for to keep it sensible.
    I can not wait to read much more from you. This is actually a great site.
    0

    0

    You have already voted!

    Reply
  6. I just wanted to thank you once more for the amazing web site you have built here.
    It’s full of ideas for those who are truly interested in this particular subject, specifically this very post.
    You’re really all actually sweet and thoughtful of others in addition to the fact that reading the
    blog posts is a wonderful delight to me. And thats a generous
    reward! Dan and I will certainly have excitement
    making use of your guidelines in what we should do in a month’s time.
    Our record is a distance long so your tips might be put to
    fine use.
    0

    0

    You have already voted!

    Reply
  7. I do agree with all the ideas you have offered
    in your post. They are very convincing and can definitely work.
    Nonetheless, the posts are too short for novices.
    May you please lengthen them a little from next time? Thank you for the post.
    0

    0

    You have already voted!

    Reply
  8. Wow, this paragraph is pleasant, my sister is analyzing these kinds of things,
    therefore I am going to let know her.
    0

    0

    You have already voted!

    Reply
  9. We are a group of volunteers and starting a new scheme in our
    community. Your web site offered us with valuable information to work on.
    You have performed an impressive task and our whole community
    will be grateful to you.
    0

    0

    You have already voted!

    Reply
  10. An interesting discussion is definitely worth comment. I do believe that you need
    to write more on this subject matter, it may not be
    a taboo subject but typically folks don’t discuss such subjects.
    To the next! All the best!!
    0

    0

    You have already voted!

    Reply
  11. It’s wonderful that you are getting thoughts from this piece of writing as well as from our dialogue
    made here.
    0

    0

    You have already voted!

    Reply
  12. I just could not leave your website before suggesting that I really enjoyed the usual
    info a person supply to your visitors? Is going to be again incessantly in order to check out new posts
    0

    0

    You have already voted!

    Reply
  13. Your method of telling all in this paragraph is
    genuinely fastidious, every one can without difficulty be aware of it, Thanks a lot.
    0

    0

    You have already voted!

    Reply
  14. You ought to be a part of a contest for one of the finest blogs online.
    I most certainly will highly recommend this web site!
    0

    0

    You have already voted!

    Reply
  15. I want to to thank you for this fantastic read!!

    I certainly loved every bit of it. I’ve got you saved as a
    favorite to check out new things you post…

    0

    0

    You have already voted!

    Reply
  16. You could definitely see your expertise in the work you write.

    The arena hopes for even more passionate writers like you who are
    not afraid to mention how they believe. At all times go after your heart.

    0

    0

    You have already voted!

    Reply
  17. Fantastic beat ! I would like to apprentice at the
    same time as you amend your site, how could i subscribe for a blog website?
    The account aided me a applicable deal. I have been a little bit acquainted of this your broadcast provided shiny
    transparent idea
    0

    0

    You have already voted!

    Reply
  18. Hello there, I found your website by way of Google even as searching for
    a related matter, your website got here up,
    it seems to be good. I’ve bookmarked it in my google bookmarks.

    Hello there, simply changed into aware of your weblog via Google,
    and found that it’s really informative. I am going to watch out for brussels.
    I’ll appreciate in the event you continue this in future.

    Many other people might be benefited out of your writing.
    Cheers!

    0

    0

    You have already voted!

    Reply
  19. Marvelous, what a weblog it is! This blog provides useful data to us, keep it up.
    0

    0

    You have already voted!

    Reply
  20. It’s appropriate time to make some plans for the future and it
    is time to be happy. I have read this post and if I
    could I wish to suggest you some interesting things or tips.

    Perhaps you can write next articles referring to this article.
    I desire to read more things about it!

    0

    0

    You have already voted!

    Reply
  21. Everyone loves what you guys are usually up too. This sort of clever work and reporting!
    Keep up the awesome works guys I’ve you guys to blogroll.
    0

    0

    You have already voted!

    Reply
  22. Hеllo mates, how is everything, and what you desirе to say about this
    piece of writing, in my view its actually remarkable in favor
    of me.
    0

    0

    You have already voted!

    Reply
  23. I visited multiple web sites however the audio feature for audio songs existing at this site is truly fabulous.
    0

    0

    You have already voted!

    Reply
  24. Have you ever thought about including a little bit more than just your articles?
    I mean, what you say is fundamental and everything.
    Nevertheless just imagine if you added some
    great graphics or video clips to give your posts more, “pop”!
    Your content is excellent but with pics and videos, this blog could undeniably be one of the best
    in its niche. Amazing blog!
    0

    0

    You have already voted!

    Reply
  25. Excellent, what a website it is! This blog presents helpful data to us,
    keep it up.
    0

    0

    You have already voted!

    Reply
  26. Remarkable! Its actually awesome article, I have got much clear idea concerning from this article.
    0

    0

    You have already voted!

    Reply
  27. Good day! Would you mind if I share your blog with my twitter group?
    There’s a lot of people that I think would really appreciate your content.
    Please let me know. Thanks
    0

    0

    You have already voted!

    Reply
  28. Wow! After all I got a webpage from where I can genuinely get valuable information regarding my study and knowledge.
    0

    0

    You have already voted!

    Reply
  29. cvtogel cvtogel cvtogel
    This website was… how do you say it? Relevant!!
    Finally I have found something that helped me.
    Thank you!
    0

    0

    You have already voted!

    Reply
  30. Right away I am going away to do my breakfast, when having my breakfast coming yet again to read additional news.
    0

    0

    You have already voted!

    Reply
  31. Hi! This post could not be written any better! Reading this post reminds me of my previous room mate!
    He always kept chatting about this. I will
    forward this article to him. Fairly certain he will have a good read.

    Thanks for sharing!

    0

    0

    You have already voted!

    Reply
  32. Hello to all, the contents present at this website are genuinely amazing for people experience, well,
    keep up the good work fellows.
    0

    0

    You have already voted!

    Reply
  33. First off I want to say awesome blog! I had a quick question that I’d
    like to ask if you don’t mind. I was interested to find out how you center yourself and clear
    your mind prior to writing. I have had a tough time clearing
    my mind in getting my thoughts out there. I do enjoy writing however it just seems like the
    first 10 to 15 minutes tend to be wasted simply just trying to figure out how to begin. Any ideas or tips?
    Thank you!
    0

    0

    You have already voted!

    Reply
  34. It’s difficult to find knowledgeable people about this topic, but you sound like you
    know what you’re talking about! Thanks
    0

    0

    You have already voted!

    Reply
  35. Just wish to say your article is as amazing.
    The clarity in your post is simply great and i could
    assume you’re an expert on this subject. Well
    with your permission let me to grab your feed to keep updated with forthcoming post.
    Thanks a million and please carry on the rewarding work.
    0

    0

    You have already voted!

    Reply
  36. I blog quite often and I genuinely appreciate your content.

    Your article has really peaked my interest. I’m going to take a note of
    your website and keep checking for new information about
    once per week. I opted in for your RSS feed too.

    0

    0

    You have already voted!

    Reply
  37. I’ll immediately grasp your rss feed as I can not find your email subscription link or
    e-newsletter service. Do you have any? Please let me realize in order that I may just subscribe.

    Thanks.

    0

    0

    You have already voted!

    Reply
  38. Fantastic goods from you, man. I have understand your stuff previous to
    and you’re just too excellent. I actually like what you have acquired here,
    certainly like what you are stating and the way in which you say it.
    You make it entertaining and you still take care of to keep it smart.
    I can’t wait to read far more from you. This is really a great website.
    0

    0

    You have already voted!

    Reply
  39. It’s an amazing post in support of all the internet people; they
    will get benefit from it I am sure.
    0

    0

    You have already voted!

    Reply
  40. We are a bunch of volunteers and starting a new scheme in our
    community. Your website provided us with valuable info to work
    on. You’ve performed a formidable activity and our entire neighborhood might be grateful to
    you.
    0

    0

    You have already voted!

    Reply
  41. I’m gone to say to my little brother, that he should also pay a visit
    this blog on regular basis to obtain updated from newest reports.
    0

    0

    You have already voted!

    Reply
  42. Thanks very interesting blog!
    0

    0

    You have already voted!

    Reply
  43. I loved as much as you will receive carried out right here.
    The sketch is tasteful, your authored material stylish.
    nonetheless, you command get bought an impatience over that
    you wish be delivering the following. unwell unquestionably come
    more formerly again since exactly the same nearly a lot often inside case you shield this increase.
    0

    0

    You have already voted!

    Reply
  44. Wonderful post however I was wanting to know if you could write a litte more on this topic?

    I’d be very thankful if you could elaborate a little bit
    more. Thanks!

    0

    0

    You have already voted!

    Reply
  45. Hi there colleagues, nice article and nice urging commented here,
    I am actually enjoying by these.
    0

    0

    You have already voted!

    Reply

Leave a Reply

Your email address will not be published. Required fields are marked *

You may use these HTML tags and attributes: <a href="" title=""> <abbr title=""> <acronym title=""> <b> <blockquote cite=""> <cite> <code> <del datetime=""> <em> <i> <q cite=""> <s> <strike> <strong>

Thanks for submitting your comment!